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Geometry of Quantum States: An Introduction to Quantum Entanglement, Second Edition


Cambridge | English | 2017 | ISBN-10: 1107026253 | 637 Pages | PDF | 16.14 mb
by Ingemar Bengtsson (Author), Karol ?yczkowski (Author)

Quantum information theory is a branch of science at the frontier of physics, mathematics, and information science, and offers a variety of solutions that are impossible using classical theory. This book provides a detailed introduction to the key concepts used in processing quantum information and reveals that quantum mechanics is a generalisation of classical probability theory. The second edition contains new sections and entirely new chapters: the hot topic of multipartite entanglement; in-depth discussion of the discrete structures in finite dimensional Hilbert space, including unitary operator bases, mutually unbiased bases, symmetric informationally complete generalized measurements, discrete Wigner function, and unitary designs; the Gleason and Kochen-Specker theorems; the proof of the Lieb conjecture; the measure concentration phenomenon; and the Hastings' non-additivity theorem. This richly-illustrated book will be useful to a broad audience of graduates and researchers interested in quantum information theory. Exercises follow each chapter, with hints and answers supplied.


English | 2014 | ISBN: 3662450208 | PDF | 182 Pages | 9.9 mb In this thesis, the author introduces two strategies used to construct various types of N-heterocycles, based on the chemistry of zirconacycles and 2,6-diazasemibullvalenes. In the first part, the author presents the development of multi-component cyclization of a zirconacyclobutene-silacyclobutene fused compound, nitriles and unsaturated compounds. These reactions provide synthetically useful methodology for various N-heterocycles such as 3-acyl pyrrole, pyrrolo[3,2-d]pyridazine and dihydropyrroloazepine, which are all difficult to synthesize by other means. The isolation and characterization of the key three-fused-ring Zr/Si-containing intermediates are also described in detail. These results show that the zirconacyclobutene-silacyclobutene fused compound behaves as a "chemical transformer" upon treatment with various substrates via the "coordination-induced skeleton rearrangement" mechanism. In the second part, the author demonstrates the synthesis and isolation of a series of 2,6-diazasemibullvalenes (NSBVs) from the reaction of 1,4-dilithio-1,3-dienes and nitriles, highlighting the significant progress made for the first time in this work: (1) determination of X-ray crystal structure of a substituted 2,6-diazasemibullvalene; (2) measurement of the activation barrier of its rapid intramolecular aza-Cope rearrangement in solution; (3) exploration of several reaction types of NSBV with diverse ring-expansion products and "bowl-shape" or "cage-shape" N-containing polycyclic skeletons; (4) demonstration of the localized structure as the predominant form and the homoaromatic delocalized structure as a minor component in the equilibrium using theoretical analysis. Based on well-founded results, this work sheds new light on this controversial topic.

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